OMB APPROVAL OMB Number: 3235-0578 Expires: May 31, 2007 Estimated average burden hours per response..... 21.09 UNITED STATES SECURITIES AND EXCHANGE COMMISSION Washington, D.C. 20549 FORM N-Q CERTIFIED SHAREHOLDER REPORT OF REGISTERED MANAGEMENT INVESTMENT COMPANIES Investment Company Act file number 811-21321 Pioneer Municipal High Income Trust (Exact name of registrant as specified in charter) 60 State Street, Boston, MA 02109 (Address of principal executive offices) (ZIP code) Dorothy E. Bourassa, Pioneer Investment Management, Inc., 60 State Street, Boston, MA 02109 (Name and address of agent for service) Registrant's telephone number, including area code: (617) 742-7825 Date of fiscal year end: April 30 Date of reporting period: July 31, 2006 Form N-Q is to be used by management investment companies, other than small business investment companies registered on Form N-5 (239.24 and 274.5 of this chapter), to file reports with the Commission, not later than 60 days after close of the first and third fiscal quarters, pursuant to Rule 30b1-5under the Investment Company Act of 1940 (17 CFR 270.30b-5). The Commission may use the information provided on Form N-Q in its regulatory, disclosure review, inspection, and policymaking roles. A registrant is required to disclose the information specified by Form N-Q, and the Commission will make this information public. A registrant is not required to respond to the collection of information contained in Form N-Q unless the Form displays a currently valid Office of Management and Budget ("OMB") control number. Please direct comments concerning the accuracy of the information collection burden estimate and any suggestions for reducing the burden to Secretary, Securities and Exchange Commission, 450 Fifth Street, NW, Washington, DC 20549-0609. The OMB has reviewed this collection of information under the clearance requirements of 44 U.S.C. ss. 3507. ITEM 1. Schedule of Investments. Pioneer Municipal High Income Trust SCHEDULE OF INVESTMENTS 7/31/06 (unaudited) Principal Amount Value TAX EXEMPT OBLIGATIONS - 128.0% of Net Assets Alabama - 0.5% 1,500,000 Camden Alabama Industrial Development Board, 6.125%, 1 $1,624,710 Arizona - 6.5% 5,000,000 Apache County Industrial Development Authority, 5.85%, $5,002,000 5,000,000 Apache County Industrial Development Authority, 5.875% 5,002,100 7,000,000 (a)Downtown Phoenix Hotel Corp., RIB, 6.103%, 7/1/40 (144 7,357,630 3,000,000 + Maricopa County Industrial Development Authority, 7.87 3,132,690 1,000,000 Pima County Industrial Development Authority, 7.25%, 7 1,072,200 500,000 Yavapai County Industrial Development Authority, 6.0%, 531,655 $22,098,275 California - 10.8% 7,270,000 California State General Obligation, 5.25%, 2/1/28 $7,581,011 5,000,000 California Statewide Communities Development Authority 5,078,000 5,150,000 Golden State Tobacco Securitization Corp., 7.8%, 6/1/4 6,156,516 7,000,000 Golden State Tobacco Securitization Corp., 7.875%, 6/1 8,398,670 2,000,000 San Diego Unified School District, 5.0%, 7/1/25 2,085,040 2,500,000 University of California Revenue, 5.0%, 5/15/25 2,580,075 5,000,000 Valley Health System Hospital Revenue, 6.5%, 5/15/25 5,006,050 $36,885,362 Connecticut - 4.0% 2,000,000 Bridgeport Senior Living Facility Revenue, 7.25%, 4/1/ $1,506,120 2,205,000 Connecticut State Health & Educational Facilities Auth 2,222,927 4,800,000 Connecticut State Health & Educational Facilities Auth 4,782,048 5,000,000 Mohegan Tribe Indians Gaming Authority, 6.25%, 1/1/31 5,311,400 $13,822,495 Delaware - 0.3% 500,000 Sussex County Delaware Revenue, 5.9%, 1/1/26 $509,735 600,000 Sussex County Delaware Revenue, 6.0%, 1/1/35 611,628 $1,121,363 District of Columbia - 3.6% 5,000,000 District of Columbia Tobacco Settlement Financing Corp $5,688,400 6,000,000 District of Columbia Tobacco Settlement Financing Corp 6,518,400 $12,206,800 Florida - 2.8% 2,000,000 Beacon Lakes Community Development, 6.9%, 5/1/35 $2,172,100 1,650,000 Polk County Industrial Development Revenue, 5.85%, 12/ 1,680,657 5,500,000 Tallahassee Health Facilities Revenue, 6.375%, 12/1/30 5,843,695 $9,696,452 Georgia - 2.0% 4,240,000 (a)Atlanta Georgia Water & Waste Revenue, RIB, 6.193%, 11 $4,502,541 2,325,000 Brunswick & Glynn County Development Authority Revenue 2,291,241 $6,793,782 Idaho - 1.6% 5,000,000 Power County Industrial Development Corp., 6.45%, 8/1/ $5,324,100 Illinois - 5.9% 1,000,000 Centerpoint Intermodal Center, 8.0%, 6/15/23 (144A) $1,010,200 5,000,000 Chicago Illinois O'Hare International Airport Revenue, 5,124,350 1,000,000 Illinois Finance Authority Revenue, 6.0%, 11/15/27 1,007,520 1,000,000 Illinois Finance Authority Revenue, 6.0%, 11/15/39 1,000,350 1,500,000 Illinois Health Facilities Authority Revenue, 6.9%, 11 1,632,765 16,880,000(b)Metropolitan Pier & Exposition Authority Dedicated Sta10,520,798 $20,295,983 Indiana - 1.6% 1,000,000 Indiana State Development Finance Authority Revenue, 5 $1,028,800 4,300,000 Indiana State Development Finance Authority Revenue, 5 4,439,965 $5,468,765 Pioneer Municipal High Income Trust SCHEDULE OF INVESTMENTS 7/31/06 (unaudited) (continued) Principal Amount Value Massachusetts - 11.1% 5,000,000 Massachusetts Bay Transportation Authority, 5.0%, 7/1/ $5,364,250 2,335,000 Massachusetts Health & Educational Facilities Authorit 2,402,995 7,050,000 Massachusetts Health & Educational Facilities Authorit 7,306,972 3,500,000 Massachusetts Health & Educational Facilities Authorit 3,742,095 5,000,000 Massachusetts Health & Educational Facilities Authorit 5,417,900 75,000 Massachusetts State Development Finance Agency, 5.25%, 69,270 9,810,000 (a)Massachusetts State Development Finance Agency, RIB, 610,633,255 3,055,000 Massachusetts State Housing Finance Agency, 5.25%, 12/ 3,102,078 $38,038,815 Michigan - 3.6% 1,500,000 John Tolfree Health System Corp., 6.0%, 9/15/23 $1,523,520 2,000,000 Michigan State Hospital Finance Authority Revenue, 5.5 1,927,160 4,010,000 Michigan State Hospital Finance Authority Revenue, 6.0 4,010,802 7,720,000 (c)Wayne Charter County Michigan Special Airport Faciliti 4,800,296 $12,261,778 Minnesota - 2.3% 1,675,000 Duluth Economic Development Authority Health Care Faci $1,787,811 8,760,000 (c)Minneapolis/St. Paul Metropolitan Airports, 7.0%, 4/1/ 6,013,565 $7,801,376 Mississippi - 0.9% 3,000,000 Mississippi Business Finance Corp. Pollution Control R $3,009,210 Missouri - 1.5% 5,500,000 St. Louis Industrial Development Authority Revenue, 7. $5,166,810 Montana - 0.5% 1,600,000 Two Rivers Authority, Inc. Correctional Facility Impro $1,556,816 Nevada - 1.4% 1,000,000 Clark County Industrial Development Revenue, 5.45%, 3/ $1,047,770 1,850,000 Clark County Industrial Development Revenue, 5.5%, 10/ 1,824,784 2,000,000 Nevada State Department of Business & Industry, 7.25%, 2,037,960 $4,910,514 New Hampshire - 0.9% 3,000,000 Manchester School Facilities Revenue, 5.125%, 6/1/28 $3,118,530 New Jersey - 10.1% 2,000,000 New Jersey Economic Development Authority Revenue, 6.2 $2,045,440 13,350,000 New Jersey Economic Development Authority Revenue, 6.213,643,833 1,000,000 New Jersey Economic Development Authority Revenue, 6.4 1,026,340 6,150,000 New Jersey Economic Development Authority Revenue, 7.0 6,443,109 10,000,000 Tobacco Settlement Financing Corp., 6.75%, 6/1/39 11,216,500 $34,375,222 New Mexico - 0.4% 1,350,000 Santa Fe Educational Facilities Revenue, 5.75%, 10/1/2 $1,404,257 New York - 8.8% 2,000,000 New York City Industrial Development Agency, 5.375%, 6 $2,058,720 6,225,000 New York City Industrial Development Agency, 6.9%, 8/1 6,209,126 5,000,000 New York City Trust Cultural Resources Revenue, 5.125% 5,163,200 7,040,000 (a)New York State Dormitory Authority Revenue, RIB, 6.41% 8,275,520 2,000,000 Suffolk County Industrial Development Agency, 7.25%, 1 2,046,400 6,000,000 Triborough Bridge & Tunnel Authority Revenue, 5.25%, 1 6,303,240 $30,056,206 North Carolina - 2.6% 4,030,000 Charlotte North Carolina Special Facilities Revenue, 5 $3,979,464 4,600,000 Charlotte North Carolina Special Facilities Revenue, 7 4,932,764 $8,912,228 Pioneer Municipal High Income Trust SCHEDULE OF INVESTMENTS 7/31/06 (unaudited) (continued) Principal Amount Value Oklahoma - 6.3% 3,000,000 + Oklahoma Development Finance Authority Revenue, 5.625% $3,178,890 8,000,000 + Oklahoma Development Finance Authority Revenue, 5.625% 8,477,040 4,100,000 Tulsa Municipal Airport Revenue, 5.65%, 12/1/35 4,113,653 1,225,000 Tulsa Municipal Airport Revenue, 6.25%, 6/1/20 1,227,916 4,350,000 Tulsa Municipal Airport Revenue, 7.35%, 12/1/11 4,349,217 $21,346,716 Oregon - 4.3% 1,000,000 Klamath Falls Electric Revenue, 5.75%, 1/1/13 $928,730 7,000,000 Klamath Falls Electric Revenue, 6.0%, 1/1/25 6,282,500 7,500,000 Western Generation Agency Cogeneration Project Revenue 7,525,725 $14,736,955 Pennsylvania - 5.8% 1,550,000 Allegheny County Hospital Development Authority Revenu $1,522,767 12,300,000 Allegheny County Hospital Development Authority Revenu14,534,910 1,000,000 Columbia County Hospital Authority Health Care Revenue 882,220 1,000,000 Hazleton Health Services Authority Hospital Revenue, 5 978,040 1,280,000 Langhorne Manor Borough Higher Education & Health Auth 1,280,115 500,000 Pennsylvania Higher Educational Facilities Authority R 517,490 $19,715,542 Rhode Island - 1.3% 4,000,000 Central Falls Detention Facilities Revenue, 7.25%, 7/1 $4,406,000 South Carolina - 2.9% 3,000,000 + Greenville County School District, 5.5%, 12/1/28 $3,286,860 5,185,000 + South Carolina Jobs Economic Development Authority Rev 5,937,188 665,000 South Carolina Jobs Economic Development Authority Rev 739,586 $9,963,634 Tennessee - 3.8% 7,000,000 Johnson City Health & Educational Facilities Board Hos $8,094,100 4,480,000 Knox County Health Educational & Housing Facilities Bo 4,837,638 $12,931,738 Texas - 12.2% 7,500,000 Alliance Airport Authority Special Facilities Revenue, $7,537,575 1,345,000 Bexar County Housing Finance Corp., 8.0%, 12/1/36 1,368,564 1,000,000 Dallas-Fort Worth International Airport Revenue, 6.0%, 990,680 5,000,000 Dallas-Fort Worth International Airport Revenue, 6.15% 5,013,350 4,000,000 Decatur Hospital Authority Revenue, 7.0%, 9/1/25 4,319,360 1,000,000 + Georgetown Health Facilities Development Corp., 6.25%, 1,080,600 3,750,000 Houston Airport System Special Facilities Revenue, 5.7 3,610,650 5,340,000 Lubbock Health Facilities Development Corp., 6.625%, 7 5,434,625 2,450,000 (a)Northside Independent School District, RIB, 6.604%, 6/ 2,711,047 500,000 Sabine River Authority Pollution Control Revenue, 6.15 539,575 7,040,000 (a)Texas State, RIB, 6.077%, 4/1/30 (144A) 7,709,082 1,500,000 Willacy County Local Government Corp. Revenue, 6.0%, 3 1,518,825 $41,833,933 Vermont - 0.5% 1,500,000 Vermont Educational & Health Buildings Financing Agenc $1,656,915 Virginia - 1.5% 1,000,000 Peninsula Ports Authority, 6.0%, 4/1/33 $1,062,960 4,000,000 + Pocahontas Parkway Association of Virginia Toll Road R 4,208,640 $5,271,600 Washington - 5.7% 4,710,000 Spokane Public Facilities District Hotel/Motel Tax & S $5,142,143 7,025,000 Tobacco Settlement Authority Revenue, 6.625%, 6/1/32 7,654,159 14,315,000 Washington State General Obligation, 0.0%, 6/1/22 6,765,412 $19,561,714 TOTAL TAX-EXEMPT OBLIGATIONS (Cost $397,630,910) $437,374,596 Pioneer Municipal High Income Trust SCHEDULE OF INVESTMENTS 7/31/06 (unaudited) (continued) Shares TAX-EXEMPT MONEY MARKET MUTUAL FUND - 0.3% of Net Assets 1,080,401 BlackRock Provident Institutional Municipal Fund $1,080,401 TOTAL TAX-EXEMPT MONEY MARKET MUTUAL FUND (Cost $1,080,401) $1,080,401 TOTAL INVESTMENTS IN SECURITIES - 128.3% (Cost $398,711,311) (d) (e) $438,454,997 OTHER ASSETS AND LIABILITIES - 1.3% $4,275,134 PREFERRED SHARES AT REDEMPTION VALUE, INCLUDING DIVIDENDS PAYABLE - (29.6)% $(101,050,559) NET ASSETS APPLICABLE TO COMMON SHAREOWNERS - 100.0% $341,679,572 NR Security not rated by S&P or Moody's. (144A) Security is exempt from registration under Rule 144A of the Securities Act of 1933. Such securities may be resold normally to qualified institutional buyers in a transaction exempt from registration. At July 31, 2006 the value of these securities amounted to $42,199,275 or 12.4% of net assets applicable to common shareowners. + Prerefunded bonds have been collateralized by U.S. Treasury securities which are held in escrow to pay interest and principal on the tax exempt issue and to retire the bonds in full at the earliest refunding date. (a) The interest rate is subject to change periodically and inversely based upon prevailing market rates. The interest rate shown was the rate at July 31, 2006. (b) Debt obligation initially issued at one coupon which converts to a higher coupon at a specific date. The rate shown is the rate at period end. (c) Security is in default and is non-income producing. (d) At July 31, 2006, the net unrealized gain on investments based on cost for federal income tax purposes of $397,221,262 was as follows: Aggregate gross unrealized gain for all investments in which there is an excess of value over tax cost 48,144,789 Aggregate gross unrealized loss for all investments in which there is an excess of tax cost over value -6,911,054 Net unrealized gain 41,233,735 For financial reporting purposes net unrealized gain on investments was $39,743,686 and cost of investments aggregated $398,711,311 RIB Residual Interest Bonds ITEM 2. CONTROLS AND PROCEDURES. (a) Disclose the conclusions of the registrant's principal executive officer or officers and principal financial officer or officers, or persons performing similar functions, about the effectiveness of the registrant's disclosure controls and procedures (as defined in Rule 30a-3(c) under the Act (17 CFR 270.30a-3(c))) as of a date within 90 days of the filing date of the report that includes the disclosure required by this paragraph, based on their evaluation of these controls and procedures required by Rule 30a-3(b) under the Act (17 CFR270.30a-3(b))) and Rule 13a-15(b) or 15d-15(b) under the Exchange Act (17 CFR240.13a-15(b) or 240.15d-15(b)). The registrant's principal executive officer and principal financial officer have concluded that the registrant's disclosure controls and procedures are effective based on their evaluation of these controls and procedures as of a date within 90 days of the filing date of this report. (b) Disclose any change in the registrant's internal controls over financial reporting (as defined in Rule 30a-3(d) under the Act (17 CFR270.30a-3(d)) that occurred during the registrant's last fiscal quarter that has materially affected, or is reasonably likely to materially affect, the registrant's internal control over financial reporting. There were no significant changes in the registrant's internal control over financial reporting that occurred during the second fiscal quarter of the period covered by this report that have materially affected, or are reasonably likely to materially affect, the registrant's internal control over financial reporting. The registrant's principal executive officer and principal financial officer, however, voluntarily are reporting the following information: In August of 2006 the registrant's investment adviser enhanced its internal procedures for reporting performance information required to be included in prospectuses. Those enhancements involved additional internal controls over the appropriateness of performance data generated for this purpose. Such enhancements were made following an internal review which identified prospectuses relating to certain classes of shares of a limited number of registrants where, inadvertently, performance information not reflecting the deduction of applicable sales charges was included. Those prospectuses were revised, and the revised prospectuses were distributed to shareholders. ITEM 3. EXHIBITS. (a) A separate certification for each principal executive officer and principal financial officer of the registrant as required by Rule 30a-2 under the Act (17 CFR 270.30a-2). Filed herewith. SIGNATURES [See General Instruction F] Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized. (Registrant) Pioneer Municipal High Income Trust By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr, President Date September 29, 2006 Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, this report has been signed below by the following persons on behalf of the registrant and in the capacities and on the dates indicated. By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr., President Date September 29, 2006 By (Signature and Title)* /s/ Vincent Nave Vincent Nave, Treasurer Date September 29, 2006 * Print the name and title of each signing officer under his or her signature.